If it is SS the only way it will rust is if it was over heated while welding, the welder used the wrong wire, or it is an inferior SS quality, ie. not 300 series. Other than that, the hardware can rust if it is not SS as well. On very extreme conditions the SS may pit, or form some thin surface "rust", this easily cleans out with any iron contaminant remover, metal polish, or super fine steel wool.
I have wrapped SS headers, including in PR while living less than 2 miles from the sea shore and never saw actual corrosion of the tubing.